Sodium hydride → 4-(3,6-Dimethoxyphenylsulphanyl)-2-amino-nitrobenzene

HRID 1795866

反応式

HRID 1795866 の反応式
OC1C=CC(S[C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-:17])=[O:16])=[C:11]([NH2:18])[CH:10]=2)=CC=1.[H-].[Na+].[CH3:21][O:22][C:23]1[CH:24]=[C:25]([SH:31])[C:26]([O:29][CH3:30])=[CH:27][CH:28]=1>>[CH3:21][O:22][C:23]1[CH:24]=[C:25]([S:31][C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-:17])=[O:16])=[C:11]([NH2:18])[CH:10]=2)[C:26]([O:29][CH3:30])=[CH:27][CH:28]=1

参加物

4

反応物 3

HCID 24758Sodium hydrideHCID 5190092,5-DimethoxythiophenolHCID 221806834-(4-Hydroxyphenylsulphanyl)-2-amino-nitrobenzene

生成物 1

HCID 221807004-(3,6-Dimethoxyphenylsulphanyl)-2-amino-nitrobenzene

実験手順

Using the general method described for 4-(4-hydroxyphenylsulphanyl)-2-amino-nitrobenzene in Example 2, except that one equivalent of NaH was used, 4-(3,6-dimethoxyphenylsulphanyl)-2-amino-nitrobenzene (4.19 g) was prepared from 3,6-dimethoxybenzenethiol (2.55 g; 15 mmol).

出典と根拠

ORDレコード
ord-5c4db8bb278e4e6fa09fc86a1ca03b64
出典データセット
uspto-grants-2006_04
特許番号
US07030123B2

関連ノート

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