Methyl 2-ethenyl-3-nitrobenzoate → HCID 22170201、化合物
反応式
[N+:1]([C:4]1[C:5]([CH:14]=[CH2:15])=[C:6]([CH:11]=[CH:12][CH:13]=1)[C:7]([O:9][CH3:10])=[O:8])([O-])=O>CCOC(C)=O.CCO.[Pd]>[NH2:1][C:4]1[C:5]([CH2:14][CH3:15])=[C:6]([CH:11]=[CH:12][CH:13]=1)[C:7]([O:9][CH3:10])=[O:8]参加物
4
実験手順
A mixture of methyl 3-nitro-2-vinylbenzoate (1.1 g, 5.31 mmol), and 5% Pd/C (100 mg) in EtOAc/EtOH 1:1 (50 ml) was hydrogenated at 3 atm over night. The mixture was filtered through Celite, and the filtrate was concentrated to give the title compound 0.93 g (97%) as a colourless oil.
後処理
- waitwas hydrogenated at 3 atm over night
- filtrationThe mixture was filtered through Celite
- concentrationthe filtrate was concentrated
出典と根拠
- ORDレコード
- ord-70a7cb9a19d644eebe299f39c33200d8
- 出典データセット
- uspto-grants-2006_05
- 特許番号
- US07037925B2
反応ノート
読み込み中…