Benzoyl Peroxide → Benzoic acid, 2-broMo-6-(broMoMethyl)-, Methyl ester

HRID 1826526ノート

反応式

HRID 1826526 の反応式
[CH3:1][O:2][C:3](=[O:12])[C:4]1[C:9]([CH3:10])=[CH:8][CH:7]=[CH:6][C:5]=1[Br:11].[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[CH3:1][O:2][C:3](=[O:12])[C:4]1[C:9]([CH2:10][Br:13])=[CH:8][CH:7]=[CH:6][C:5]=1[Br:11]

参加物

5

反応物 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 11564857Methyl 2-bromo-6-methylbenzoate

生成物 1

HCID 23574705Benzoic acid, 2-broMo-6-(broMoMethyl)-, Methyl ester

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

反応条件

温度
80 °C

実験手順

2-Bromo-6-methyl-benzoic acid methyl ester (21.8 mmol), and N-bromosuccinimide (21.8 mmol), benzoyl peroxide (1.1 mmol) were combined in 50 mL carbontetrachloride and heated to 80° C. overnight. The resulting precipitate was filtered off, and filtrate concentrated to an oil.

後処理

  1. filtrationThe resulting precipitate was filtered off
  2. concentrationfiltrate concentrated to an oil

出典と根拠

ORDレコード
ord-04167b4522244ba8b1d2d3b4c4e95255
出典データセット
uspto-grants-2006_05
特許番号
US07049318B2

反応ノート

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