Triethylamine → ((3,4-Difluorophenyl)ethynyl)trimethylsilane

HRID 182853

反応式

HRID 182853 の反応式
[Br:8][c:9]1[cH:10][c:11]([F:16])[c:12]([F:15])[cH:13][cH:14]1.[CH3:17][Si:18]([CH3:19])([CH3:20])[C:21]#[CH:22].[CH3:1][CH2:2][N:3]([CH2:4][CH3:5])[CH2:6][CH3:7].[CH3:23][CH2:24][O:25][C:26](=[O:27])[CH3:28].[Cu:29][I:30].[Pd:31]([Cl:32])[Cl:33].[c:34]1([P:35]([c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[c:42]2[cH:43][cH:44][cH:45][cH:46][cH:47]2)[cH:48][cH:49][cH:50][cH:51][cH:52]1.[c:53]1([P:54]([c:55]2[cH:56][cH:57][cH:58][cH:59][cH:60]2)[c:61]2[cH:62][cH:63][cH:64][cH:65][cH:66]2)[cH:67][cH:68][cH:69][cH:70][cH:71]1>>[c:9]1([C:22]#[C:21][Si:18]([CH3:17])([CH3:19])[CH3:20])[cH:10][c:11]([F:16])[c:12]([F:15])[cH:13][cH:14]1

参加物

8

反応物 7

HCID 8471TriethylamineHCID 8857Ethyl AcetateHCID 11776Triphenylphosphine2 回HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 676754-Bromo-1,2-difluorobenzene

生成物 1

HCID 67047877((3,4-Difluorophenyl)ethynyl)trimethylsilane

出典と根拠

ORDレコード
ord-a9b053a5dba34ab4af01d2840b0ddfb0
出典データセット
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

関連ノート

読み込み中…