1,1,3,3-Tetramethylguanidine → HCID 21388583、化合物

HRID 1833283ノート

反応式

HRID 1833283 の反応式
C[O:2][C:3]([P:5](=[O:10])([O:8][CH3:9])[O:6][CH3:7])=O.[CH3:11][N:12]([CH3:18])[C:13]([N:15]([CH3:17])[CH3:16])=[NH:14]>O1CCCC1>[CH3:11][N:12]([CH3:18])[C:13](=[N:14][C:3]([P:5](=[O:10])([O:8][CH3:9])[O:6][CH3:7])=[O:2])[N:15]([CH3:17])[CH3:16]

参加物

4

反応物 2

HCID 664601,1,3,3-TetramethylguanidineHCID 451443Trimethyl phosphonoformate

生成物 1

HCID 21388583HCID 21388583、化合物

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

A solution of 54 parts of dimethyl methoxycarbonylphosphonate and 38 parts of 1,1,3,3-tetramethylguanidine in 1000 parts of anhydrous tetrahydrofuran was refluxed for one hour. The solvent was removed under reduced pressure to yield 77 parts of dimethyl 1,1-bis(dimethylamino)-methyleneaminocarbonylphosphonate, nD27 = 1.4855.

後処理

  1. customThe solvent was removed under reduced pressure

出典と根拠

ORDレコード
ord-93d132b65d404e8f90122602d46e94ba
出典データセット
uspto-grants-1978_01
特許番号
US04066434

反応ノート

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