Carbon Disulfide → (2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

HRID 1834549

反応式

HRID 1834549 の反応式
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH2:11].[C:12](=[S:14])=[S:13]>C(O)C>[CH3:1][C:2]1[NH:3][CH:4]=[N:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH:11][C:12](=[S:13])[SH:14]

参加物

4

反応物 2

HCID 6348Carbon DisulfideHCID 178433288HCID 178433288、化合物

生成物 1

HCID 15566013(2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A solution of 4-methyl-5-((2-aminoethyl)thiomethyl) imidazole (10.2 g) in ethanol(75 ml) was added slowly, with stirring, to carbon disulphide (200 ml). The mixture was set aside overnight at room temperature and the solid formed was collected and recystallised from aqueous isopropyl alcohol to afford N-[2-((5-methyl-4imidazolyl)methylthio)ethyl]dithiocarbamic acid (9.8 g)., m.p. 127°-129°.

後処理

  1. customthe solid formed
  2. customwas collected

出典と根拠

ORDレコード
ord-4c908ea815e94302afee9727e4d82d92
出典データセット
uspto-grants-1978_01
特許番号
US04070472

関連ノート

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