1,10-Decanediamine → Dodecanedioic Acid

反応式

N[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH2:8].[C:9]([OH:24])(=[O:23])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][C:20]([OH:22])=[O:21].C(N)CCC[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][NH2:35]>>[CH2:7]([NH2:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][NH2:35].[C:9]([OH:24])(=[O:23])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][C:20]([OH:22])=[O:21]

参加物

反応物 3

HCID 13171,10-Decanediamine

HCID 12736Dodecanedioic Acid2 回

HCID 16402Hexamethylenediamine

生成物 2

HCID 12736Dodecanedioic Acid

HCID 177271,12-Dodecanediamine

実験手順

PA612 is prepared in a known manner by polycondensation of an equivalent mixture of hexamethylenediamine and 1,12-dodecanedioic acid. PA1012 is prepared by polycondensation of an equivalent mixture of 1,10-decanediamine and 1,12-dodecanedioic acid, while PA1212 is obtained in the same manner from 1,12-dodecanediamine and 1,12-dodecanedioic acid.

出典と根拠

ORDレコード: ord-c974aa44476741aca8273aaa3184121f
出典データセット: uspto-grants-2004_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06783821B2

反応ノート

読み込み中…