3-(3-Nitro-phenyl)-acrylonitrile → HCID 22186098、化合物

HRID 1837516

反応式

HRID 1837516 の反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]#[N:13])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]>C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh].C1C=CC=CC=1>[N+:1]([C:4]1[CH:5]=[C:6]([CH2:10][CH2:11][C:12]#[N:13])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

参加物

4

反応物 1

HCID 556693-(3-Nitro-phenyl)-acrylonitrile

生成物 1

HCID 22186098HCID 22186098、化合物

試薬・触媒・溶媒 2

HCID 84599Chlorotris(triphenylphosphine)rhodium(I)触媒HCID 241Benzene溶媒

反応条件

温度
40 °C

実験手順

There are introduced into a cylinder 3 g of the product obtained in Step 1, 1.59 g of tris(triphenylphosphine)rhodium(I) chloride and 90 ml of benzene. The whole is heated for 5 hours at 40° C. under a hydrogen pressure of 5 bar. The solvent is evaporated off and the residue is purified by chromatography on silica gel using dichloromethane as eluant.

後処理

  1. customThe solvent is evaporated off
  2. customthe residue is purified by chromatography on silica gel

出典と根拠

ORDレコード
ord-85e8aacf647b40d99e6441bc79a44ef9
出典データセット
uspto-grants-2004_08
特許番号
US06784183B2

関連ノート

読み込み中…