Hydrochloric Acid → 1-Methoxy-3-nonyl benzene

HRID 18450ノート

反応式

HRID 18450 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([CH:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH:4]=1.Cl>CCO.[Pd]>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH:4]=1

参加物

5

反応物 2

HCID 313Hydrochloric AcidHCID 685864941-Methoxy-3-non-1-enyl benzene

生成物 1

HCID 200388771-Methoxy-3-nonyl benzene収率 100%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

A solution of 1-methoxy-3-non-1-enyl benzene (7.4 g 32 mmol) in 99% EtOH (50 mL) was added 6 M HCl (aq.; 0.5 mL) and stirred with 10% Pd/C under H2-atmosphere (1 atm) to give 7.5 g (quantitative yield) of the desired product, after filtration through Celite and evaporation to dryness of the eluate.

出典と根拠

ORDレコード
ord-501ca122717042c4b30a6e74dde14a62
出典データセット
uspto-grants-2010_06
特許番号
US07741352B2

反応ノート

読み込み中…