関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | Dimethylacetamide | HCID 31374 | — |
| 反応物 | 1-Fluoro-5-methyl-2,4-dinitrobenzene | HCID 520705 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | (E)-2-(5-fluoro-2,4-dinitrophenyl)-N,N-dimethylethenamine | HCID 15022335 | 63% |
反応手順
A mixture of 1-fluoro-5-methyl-2,4-dinitro-benzene (10 g, 50 mmol), DMA (12 g, 100 mmol) and DMF (50 mL) was heated at 100° C. for 4 h. The solution was cooled and poured into water. The precipitated red solid was collected, washed with water, and dried to give (E)-2-(5-fluoro-2,4-dinitrophenyl)-N,N-dimethylethenamine (8.0 g, 63%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08952050B2 |
|---|
| 出典データセット | uspto-grants-2015_02 |
|---|
| ORD ID | ord-7bba44fce6764bd9a5746d77d4576040 |
|---|
| 出典メモ | uspto-grants-2015_02 |
|---|
