Tetrahydrofuran → HCID 178426004、化合物

HRID 1862196ノート

反応式

HRID 1862196 の反応式
[CH2:1]([Li])[CH2:2][CH2:3][CH3:4].[Cl-:6].[Cl-].[Cl-].C[Zr:10](C)(C)(C)(C)[CH:11]1[CH:15]=[CH:14][CH:13]=[CH:12]1.O1CCC[CH2:21]1>>[Cl-:6].[Cl-:6].[CH3:1][C:2]1[C:11]([Zr+2:10])([CH3:12])[C:15]([CH3:21])=[C:14]([CH3:13])[C:3]=1[CH3:4]

参加物

4

反応物 3

HCID 8028Tetrahydrofuran2 回HCID 178418339ButyllithiumHCID 178477801HCID 178477801、化合物

生成物 1

HCID 178426004HCID 178426004、化合物

実験手順

A solution of 1.39 g of 1′H, 1′H, 2′H, 2′H-perfluorooctylcyclopentadiene from Example 5 in 50 ml of tetrahydrofuran is admixed at −78° C. with 2.1 ml of 1.65 M butyllithium solution and then admixed with a cooled suspension of 1.11 g of pentamethylcyclopentadienylzirconium trichloride in 30 ml of tetrahydrofuran. The mixture is allowed to warm to room temperature and the solvent is removed under reduced pressure. The product is isolated by means of extraction with methylene chloride and pentane.

後処理

  1. customthe solvent is removed under reduced pressure
  2. customThe product is isolated by means of extraction with methylene chloride and pentane

出典と根拠

ORDレコード
ord-47fa57dbd40946f58b382c9de54c01fc
出典データセット
uspto-grants-2003_03
特許番号
US06537943B1

反応ノート

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