Nitric Acid → HCID 20342728、化合物

HRID 1862798ノート

反応式

HRID 1862798 の反応式
CCOCC.[C:6]1([CH3:16])[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[O:12][CH:13]([CH3:15])[CH3:14].C(OC(=O)C)(=O)C.[N+:24]([O-])([OH:26])=[O:25]>C(O)(=O)C.O>[CH:13]([O:12][C:7]1[CH:8]=[CH:9][C:10]([N+:24]([O-:26])=[O:25])=[CH:11][C:6]=1[CH3:16])([CH3:14])[CH3:15]

参加物

7

反応物 4

HCID 944Nitric AcidHCID 3283Diethyl EtherHCID 7918Acetic AnhydrideHCID 141785Benzene, 1-methyl-2-(1-methylethoxy)-

生成物 1

HCID 20342728HCID 20342728、化合物

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒2 回HCID 962Water溶媒

反応条件

温度
6 °C

実験手順

To a chilled (6° C.) solution containing 31.8 g (0.2 mole) of the ether prepared as in (a) above and 28.7 g of acetic anhydride in 200 ml of glacial acetic acid was added dropwise a solution of 13.9 g (0.22 mole) of 90% nitric acid in 100 ml of glacial acetic acid. The reaction mixture was allowed to stand at ambient temperature for 12 hours, poured into water and extracted with methylene chloride. The extract was washed with 5% sodium carbonate, water, dried, and concentrated to give 21.8 g of product as an amber oil.

後処理

  1. additioncontaining
  2. extractionextracted with methylene chloride
  3. washThe extract was washed with 5% sodium carbonate, water
  4. customdried
  5. concentrationconcentrated

出典と根拠

ORDレコード
ord-caa16b0256c242529b30422987daef03
出典データセット
uspto-grants-1979_09
特許番号
US04166735

反応ノート

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