Ethyl octanoate → Octanoic hydrazide

HRID 1863201

反応式

HRID 1863201 の反応式
[C:1]([O:10]CC)(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].O.[NH2:14][NH2:15]>C(O)C>[C:1]([NH:14][NH2:15])(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

4

反応物 2

HCID 7799Ethyl octanoateHCID 24654Hydrazine hydrate (1:1)

生成物 1

HCID 80556Octanoic hydrazide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

Production of the spacer-gel derivative: Ethyl caprylate was converted into the corresponding hydrazide by hydrazinolysis, by initially admixing 10 ml. of this ethyl ester with 10 ml. of 98% hydrazine hydrate. Ethanol (22 ml.) was added as solvent, until the reaction mixture cleared, following which the solution was left at room temperature for 15 hours. The crystallized out resulting caprylhydrazide was filtered off and washed with ice water and then with aqueous methanol (1:1) of room temperature.

後処理

  1. customThe crystallized

出典と根拠

ORDレコード
ord-30a09d1cae444aae8f82551b262200ee
出典データセット
uspto-grants-1979_09
特許番号
US04168300

関連ノート

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