Carbon Tetrachloride → 1,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

HRID 1869147ノート

反応式

HRID 1869147 の反応式
C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[C:20](Cl)(Cl)([Cl:22])[Cl:21].[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:53])[Cl:52])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30](=O)[CH2:31][O:32][C:33]1[CH:38]=[CH:37][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:35][CH:34]=1>C(#N)C>[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:52])[Cl:53])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30]([CH2:31][O:32][C:33]1[CH:34]=[CH:35][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:37][CH:38]=1)=[C:20]([Cl:22])[Cl:21]

参加物

5

反応物 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 86613082HCID 86613082、化合物

生成物 1

HCID 866130861,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

312 mg of triphenylphosphine, 183 mg of carbon tetrachloride and 200 mg of 1-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-3-(4-trifluoromethyl-phenoxy)-propan-2-one are stirred in 3 ml of acetonitrile for 24 hours at 55° C. The reaction mixture is concentrated and the residue is purified over silica gel. The title compound is obtained.

後処理

  1. concentrationThe reaction mixture is concentrated
  2. customthe residue is purified over silica gel

出典と根拠

ORDレコード
ord-7bae7ae803fa4315b91414a54d8fdc88
出典データセット
uspto-grants-2009_12
特許番号
US07638514B2

反応ノート

読み込み中…