Methyl iodide → HCID 68590834、化合物
反応式
[CH3:1][C:2]1[C:7]2[S:8][CH:9]=[CH:10][C:6]=2[CH2:5][CH2:4][N:3]=1.[CH3:11][I:12]>C(OCC)(=O)C>[I-:12].[CH3:11][N+:3]1[CH2:4][CH2:5][C:6]2[CH:10]=[CH:9][S:8][C:7]=2[C:2]=1[CH3:1]参加物
4
実験手順
A mixture of 4.64 g (31 mmol) 7-methyl-4,5-dihydro-thieno[2,3-c]pyridine (prepared analogously to J.Am.Chem.Soc., 1951, 1257), 8.0 ml (128 mmol) methyl iodide and 20 ml of ethyl acetate is stirred for 15 min. The precipitate formed is suction filtered, washed with ethyl acetate and dried in vacuo.
後処理
- customprepared analogously to J.Am.Chem.Soc
- customThe precipitate formed
- filtrationfiltered
- washwashed with ethyl acetate
- customdried in vacuo
出典と根拠
- ORDレコード
- ord-0843bf2fcfc94ff0ada02d33864cdc05
- 出典データセット
- uspto-grants-2012_11
- 特許番号
- US08309542B2
反応ノート
読み込み中…