Dimethylformamide → HCID 86633441、化合物
反応式
[CH2:1]([O:3][C:4]1[C:5]([OH:18])=[C:6]([N+:15]([O-:17])=[O:16])[C:7]([N+:12]([O-:14])=[O:13])=[C:8]([CH:11]=1)[CH:9]=[O:10])[CH3:2].CN(C)C=O.C([O-])([O-])=O.[K+].[K+].[CH2:30](Br)[CH3:31]>C(OCC)C>[CH2:30]([O:18][C:5]1[C:4]([O:3][CH2:1][CH3:2])=[CH:11][C:8]([CH:9]=[O:10])=[C:7]([N+:12]([O-:14])=[O:13])[C:6]=1[N+:15]([O-:17])=[O:16])[CH3:31]参加物
6
実験手順
5-Ethoxy-4-hydroxy-2,3-dinitro-benzaldehyde (3.77 g), N,N-dimethylformamide (35 ml), K2CO3 (3.877 g) and ethyl bromide (50 ml) were refluxed 24 hours. To the reaction solution was added diethyl ether (100 ml) and then it was washed with water and 1M sodium hydroxide. The solution was dried and evaporated.
後処理
- washit was washed with water and 1M sodium hydroxide
- customThe solution was dried
- customevaporated
出典と根拠
- ORDレコード
- ord-360da99a33264717ae57c90d3191fd1f
- 出典データセット
- uspto-grants-2012_11
- 特許番号
- US08318785B2
反応ノート
読み込み中…