Acetoacetic Acid → (11s,11As)-7,8-dimethoxy-2-oxo-11-(tert-butyldimethylsilyloxymethyl)-10-(2,2,2-trichloroethoxycarbonyl)-1,2,3,10,11,11a-hexahydro-5h-pyrrolo [2,1-c][1,4]benzodiazepin-5-one

反応式

CC(CC(O)=O)=O.N=O.CC1(C)CCCC(C)(C)N1.[CH3:20][O:21][C:22]1[C:23]([O:55][CH3:56])=[CH:24][C:25]2[N:31]([C:32]([O:34][CH2:35][C:36]([Cl:39])([Cl:38])[Cl:37])=[O:33])[C@H:30]([CH2:40][O:41][Si:42]([C:45]([CH3:48])([CH3:47])[CH3:46])([CH3:44])[CH3:43])[C@@H:29]3[CH2:49][C@@H:50]([OH:52])[CH2:51][N:28]3[C:27](=[O:53])[C:26]=2[CH:54]=1>C(Cl)Cl>[CH3:20][O:21][C:22]1[C:23]([O:55][CH3:56])=[CH:24][C:25]2[N:31]([C:32]([O:34][CH2:35][C:36]([Cl:39])([Cl:37])[Cl:38])=[O:33])[C@H:30]([CH2:40][O:41][Si:42]([C:45]([CH3:48])([CH3:47])[CH3:46])([CH3:44])[CH3:43])[C@@H:29]3[CH2:49][C:50](=[O:52])[CH2:51][N:28]3[C:27](=[O:53])[C:26]=2[CH:54]=1