Thionyl Chloride → 2,6-Diethyl-4-methylbenzyl chloride
反応式
[CH2:1]([C:3]1[CH:10]=[C:9]([CH3:11])[CH:8]=[C:7]([CH2:12][CH3:13])[C:4]=1[CH2:5]O)[CH3:2].S(Cl)([Cl:16])=O>C1(C)C=CC=CC=1>[CH2:1]([C:3]1[CH:10]=[C:9]([CH3:11])[CH:8]=[C:7]([CH2:12][CH3:13])[C:4]=1[CH2:5][Cl:16])[CH3:2]参加物
4
実験手順
To a mixture of 138.41 g of 2,6-diethyl-4-methylbenzyl alcohol and 820 g of toluene was added dropwise 60.96 g of thionyl chloride at 25° C. over 4.5 hours. The resultant mixture was stirred for 15 hours. The reaction mixture was concentrated to obtain 159.58 g of 2,6-diethyl-4-methylbenzyl chloride (GC-area: 71%) as a brown oil.
後処理
- concentrationThe reaction mixture was concentrated
出典と根拠
- ORDレコード
- ord-8a9772cead8647128b59ef23caf641f5
- 出典データセット
- uspto-grants-2013_08
- 特許番号
- US08507410B2
反応ノート
読み込み中…