1-(4-Benzyloxyphenyl)-heptane-1,3-dione → 1-(4-Hydroxyphenyl)heptane-1,3-dione
反応式
C([O:8][C:9]1[CH:14]=[CH:13][C:12]([C:15](=[O:23])[CH2:16][C:17](=[O:22])[CH2:18][CH2:19][CH2:20][CH3:21])=[CH:11][CH:10]=1)C1C=CC=CC=1.[H][H]>C1(C)C=CC=CC=1.[Pd]>[OH:8][C:9]1[CH:10]=[CH:11][C:12]([C:15](=[O:23])[CH2:16][C:17](=[O:22])[CH2:18][CH2:19][CH2:20][CH3:21])=[CH:13][CH:14]=1参加物
5
実験手順
1-(4-Benzyloxyphenyl)-heptane-1,3-dione (4 g; see step (a) above) was dissolved in toluene (20 ml) and Pd/C (3%; 80 mg) was added. The mixture was stirred at room temperature until hydrogen uptake ceased. After filtration of the catalyst, the solvent was evaporated leaving 2.84 g, 100%, 1-(4-hydroxyphenyl)-heptane-1,3-dione.
後処理
- filtrationAfter filtration of the catalyst
- customthe solvent was evaporated
出典と根拠
- ORDレコード
- ord-b019de93c2b947719148b86cc23b1ed6
- 出典データセット
- uspto-grants-2013_08
- 特許番号
- US08519165B2
反応ノート
読み込み中…