Aluminium lithium hydride → HCID 21474772、化合物
反応式
[C:1]1([CH2:7][CH2:8][O:9][CH2:10][CH:11]([OH:16])[CH2:12][N:13]=[N+]=[N-])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[C:1]1([CH2:7][CH2:8][O:9][CH2:10][CH:11]([OH:16])[CH2:12][NH2:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
4
実験手順
A procedure similar to that described in Preparation 13 was repeated, except that 5.30 g of 3-(2-phenylethoxy)-2-hydroxypropylazide (prepared as described in Preparation 56), 1.85 g of lithium aluminum hydride and 120 ml of anhydrous tetrahydrofuran were used, to give 4.47 g of the title compound as a colorless oil having an Rf value of 0.09 (on silica gel thin layer chromatography, using a 10:1 by volume mixture of ethyl acetate and methanol as the developing solvent).
後処理
- customA procedure similar to that described in Preparation 13
出典と根拠
- ORDレコード
- ord-e73711e75ed346ad82f06cf59385e9d4
- 出典データセット
- uspto-grants-1996_11
- 特許番号
- US05578620
反応ノート
読み込み中…