Hydrazine hydrate (1:1) → 4-Pentyl-3-fluoroanisole
反応式
[C:1]([C:7]1[CH:12]=[CH:11][C:10]([O:13][CH3:14])=[CH:9][C:8]=1[F:15])(=O)[CH2:2][CH2:3][CH2:4][CH3:5].O.NN.OC(O)C>>[CH2:1]([C:7]1[CH:12]=[CH:11][C:10]([O:13][CH3:14])=[CH:9][C:8]=1[F:15])[CH2:2][CH2:3][CH2:4][CH3:5]参加物
4
実験手順
4-Valeryl-3-fluoroanisole (14.1 g), hydrazine hydrate (8.6 ml) potassium hydroxide (4.4 g) and 1:1 dihydroxyethane (84 ml) were reacted together as described in Example 1. 4-Pentyl-3-fluoroanisole was isolated as a colourless oil b.pt 77° C. at 0.1 mm. The product showed 1 spot only on tlc using dichloromethanepetrol (1:1) as solvent.
出典と根拠
- ORDレコード
- ord-b14077b30c89452d8b052ebadd29d10c
- 出典データセット
- uspto-grants-1982_12
- 特許番号
- US04366330
反応ノート
読み込み中…