Acetone → HCID 20468529、化合物

反応式

[SH2]=N.[CH2:3]([NH:7][C:8](C1C=CC=CC=1C(O)=O)=[O:9])[CH2:4][CH2:5][CH3:6].[C:19]1([NH2:26])[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=1[NH2:25].C([N:29]([CH2:32][CH3:33])[CH2:30]C)C.[OH2:34].[CH3:35][C:36](C)=O>>[CH2:32]([NH:29][C:30]([NH:25][C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][C:19]=1[NH:26][C:8](=[O:9])[NH:7][CH2:3][CH2:4][CH2:5][CH3:6])=[O:34])[CH2:33][CH2:35][CH3:36]

参加物

反応物 5

HCID 180Acetone

HCID 962Water

HCID 7243O-Phenylenediamine

HCID 8471Triethylamine

HCID 178449294HCID 178449294、化合物

生成物 1

HCID 20468529HCID 20468529、化合物

実験手順

11.28 g n-butylcarbamoyl-benzoic acid sulfimide was reacted with 2.16 g o-phenylene diamine and 5.6 ml triethylamine in 20 ml of a 1:1 mixture of water and acetone, as described in example 1. 5.0 g N,N'-bis(n-butylcarbamoyl)-o-phenylene diamine was obtained, melting at 163°-164° C.