Benzoyl Peroxide → HCID 23438954、化合物

HRID 1903711ノート

反応式

HRID 1903711 の反応式
[CH3:1][C:2]1[S:3][C:4]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)=[CH:5][CH:6]=1.[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:13][CH2:1][C:2]1[S:3][C:4]([C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)=[CH:5][CH:6]=1

参加物

5

反応物 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 75788052-methyl-5-phenylthiophene

生成物 1

HCID 23438954HCID 23438954、化合物

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

To a boiling solution of 2-methyl-5-phenylthiophene (2g) in dry CCl4 (100 ml) was rapidly added N-bromosuccinimide (1.94 g) and dibenzoylperoxide (0.15 g). After heating under reflux for 30 min., the mixture was cooled and filtered. Evaporation in vacuo gave the title compound as an oil (1.5 g).

後処理

  1. temperatureAfter heating
  2. temperatureunder reflux for 30 min.
  3. temperaturethe mixture was cooled
  4. filtrationfiltered
  5. customEvaporation in vacuo

出典と根拠

ORDレコード
ord-0902d85f48444f24ad68a2af63c4a5d5
出典データセット
uspto-grants-1984_03
特許番号
US04438111

反応ノート

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