2-Chlorobenzyl mercaptan → Emd 39593

HRID 1906740

反応式

HRID 1906740 の反応式
[Cl:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][SH:5].Cl[C:11]1[C:16]2[N:17]=[CH:18][N:19]([CH3:20])[C:15]=2[CH:14]=[CH:13][N:12]=1>C(O)C>[Cl:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][S:5][C:11]1[C:16]2[N:17]=[CH:18][N:19]([CH3:20])[C:15]=2[CH:14]=[CH:13][N:12]=1

参加物

4

反応物 2

HCID 5807592-Chlorobenzyl mercaptanHCID 9487924-chloro-1-methyl-1H-imidazo(4,5-c)pyridine

生成物 1

HCID 135146Emd 39593

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

2.76 g of Na is dissolved in 180 ml of ethanol; 19.1 g of o-chlorobenzylmercaptan and 16.76 g of 4-chloro-1-methyl-1H-imidazo(4,5-c)pyridine are added; the mixture is boiled for 16 hours and evaporated; and the residue is worked up in the customary manner to give 4-o-chloro-benzylthio-1-methyl-1H-imidazo(4,5-c)pyridine of m.p. 152°-155° (from ethanol).

後処理

  1. customevaporated

出典と根拠

ORDレコード
ord-356079d3f1214307a783e51e9d01b193
出典データセット
uspto-grants-1987_03
特許番号
US04654350

関連ノート

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