Hydrazine hydrate (1:1) → HCID 68753336、化合物
反応式
[C:1]([CH:5]([C:8]#[N:9])[C:6]#[N:7])([CH3:4])([CH3:3])[CH3:2].O.[NH2:11][NH2:12]>C(O)CCC>[C:1]([C:5]1[C:8]([NH2:9])=[N:11][NH:12][C:6]=1[NH2:7])([CH3:4])([CH3:3])[CH3:2]参加物
4
実験手順
A mixture of tert-butylmalononitrile (5.01 g, 41.0 mmol) and hydrazine monohydrate (10.0 mL, 205 mmol) in 1-butanol (40 mL) was heated to reflux and stirred overnight (19 hours). The mixture was cooled to ambient temperature. Concentration afforded 6.33 g (100%) of the title compound. MS (DCI) m/z 155 (M+H)+.
後処理
- temperaturewas heated
- temperatureto reflux
- concentrationConcentration
出典と根拠
- ORDレコード
- ord-75fbf83dcb7945799de9f764d2af89d9
- 出典データセット
- uspto-grants-2013_12
- 特許番号
- US08609669B2
反応ノート
読み込み中…