Sodium Hydroxide → HCID 13713019、化合物

HRID 1914807ノート

反応式

HRID 1914807 の反応式
[CH3:1][NH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[NH2:9].[CH3:10][NH:11][C:12]1[CH:20]=[CH:19][C:15]([C:16](O)=O)=[CH:14][CH:13]=1.[OH-].[Na+]>O>[CH3:10][NH:11][C:12]1[CH:20]=[CH:19][C:15]([C:16]2[N:2]([CH3:1])[C:3]3[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=3[N:9]=2)=[CH:14][CH:13]=1

参加物

5

反応物 3

HCID 14798Sodium HydroxideHCID 663454-(Methylamino)benzoic acidHCID 78498N-Methyl-o-phenylenediamine

生成物 1

HCID 13713019HCID 13713019、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
80 °C

実験手順

10.14 mL (86.5 mmol) N-Methyl-o-phenylenediamine and 13.08 g (86.5 mmol) 4-(methylamino)benzoic acid are stirred in 70.0 g polyphosphoric acid at 200° C. for 3 hours. The mixture is cooled to 80° C., poured into water and stirred over night at RT. The mixture is alkalinized with sodium hydroxide solution. The precipitate is filtered off and washed with water. The product is dried in vacuo at 50° C.

後処理

  1. filtrationThe precipitate is filtered off
  2. washwashed with water
  3. customThe product is dried in vacuo at 50° C.

出典と根拠

ORDレコード
ord-d648c7093ffc4159ad96d844d97e66a5
出典データセット
uspto-grants-2013_12
特許番号
US08614238B2

反応ノート

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