1-Chlorooctane → Octyltrichlorosilane

HRID 1937074

反応式

HRID 1937074 の反応式
[Cl-].C([P+](CCCC)(CCCC)CCCC)C1C=CC=CC=1.Cl[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30].[Cl:31][SiH:32]([Cl:34])[Cl:33]>>[CH2:23]([Si:32]([Cl:34])([Cl:33])[Cl:31])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30]

参加物

4

反応物 3

HCID 81421-ChlorooctaneHCID 24811TrichlorosilaneHCID 200231Benzyltributylphosphonium chloride

生成物 1

HCID 21354Octyltrichlorosilane収率 87%

反応条件

温度
170 °C

実験手順

In a 25 ml oven dried stainless steel tube, 0.22 g (0.67 mmol) of benzyltributylphosphonium chloride, 1.00 g (6.73 mmol) of 1-chlorooctane, and 2.71 g (20.0 mmol) of trichlorosilane were added under a dry nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 170° C. for 2 hrs. The resulting mixture was distilled to yield 1.45 g of n-octyltrichlorosilane (yield; 87%).

後処理

  1. distillationThe resulting mixture was distilled

出典と根拠

ORDレコード
ord-bedd054c771b45e180124ea33c550a0a
出典データセット
uspto-grants-2002_05
特許番号
US06392077B1

関連ノート

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