Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1937085

反応式

HRID 1937085 の反応式
[Cl-:1].[CH2:2]([P+](CCCC)(CCCC)CCCC)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:22](Cl)[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1.[Cl:30][SiH2:31][Cl:32]>>[CH2:2]([SiH:31]([Cl:32])[Cl:30])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:22]([Si:31]([Cl:1])([Cl:32])[Cl:30])[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1

参加物

5

反応物 3

HCID 7503Benzyl ChlorideHCID 61330DichlorosilaneHCID 200231Benzyltributylphosphonium chloride

生成物 2

HCID 69863Benzene, [(trichlorosilyl)methyl]-収率 53%HCID 101943102Benzyldichlorosilane収率 19%

実験手順

In the same apparatus and procedure as Example 1 above, 0.26 g (0.79 mmol) of benyltributylphosphonium chloride, 1.01 ml (7.98 mmol) of benzyl chloride, and 2.42 g (24.0 mmol) of dichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 0.29 g of benzyldichlorosilane (yield; 19%) and 0.95 g of benzyltrichlorosilane (yield; 53%).

後処理

  1. distillationThe resulting mixture was distilled

出典と根拠

ORDレコード
ord-380bfbcecc3d4ac1a46bb07f1b202964
出典データセット
uspto-grants-2002_05
特許番号
US06392077B1

関連ノート

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