N,N-diethyl-m-toluamide → Urea Urethane

HRID 1941396ノート

反応式

HRID 1941396 の反応式
CC([NH:4]P([O:9][C:10]1[CH:15]=CC(Cl)=CC=1Cl)(OC)=S)C.CC([N:33]=[C:34]=[O:35])(C1C=CC=C(C([N:30]=[C:31]=[O:32])(C)C)C=1)C.[OH-].[Na+].CCN(C(C1C=CC=C(C)C=1)=O)CC>O.CC(=O)OCC>[NH2:30][C:31]([O:9][CH2:10][CH3:15])=[O:32].[NH2:4][C:34]([NH2:33])=[O:35]

参加物

7

反応物 4

HCID 4284N,N-diethyl-m-toluamideHCID 9299ZytronHCID 14798Sodium HydroxideHCID 177191,3-Bis(1-isocyanato-1-methylethyl)benzene

生成物 1

HCID 21585015Urea Urethane

試薬・触媒・溶媒 2

HCID 962Water溶媒2 回HCID 8857Ethyl Acetate溶媒

実験手順

143.1 g of Rucoflex XS-5570-55, 154.4 g of Rucoflex S-1011-55, 9.0 g of MPdiol and 6.7 g of DMPA are reacted with 73.2 g of TMXDI and 25.2 d of HDI at 80° C. for 3 hours to prepare a prepolymer. The prepolymer is then dispersed in a solution of 3.0 NaOH and 2.75 g of EA in 736 g of water. After 5 minutes, a solution of 2.7 g of EDA and 3.06 g of DETA in 50.0 g of water is added to form a aqueous poly(urethane/urea) dispersion. A finely divided dispersion having solids content of 35.2% and a pH of 7.85 is obtained.

後処理

  1. customto prepare a prepolymer

出典と根拠

ORDレコード
ord-278dd2f947f74721b09b9fbac89b2b03
出典データセット
uspto-grants-1997_12
特許番号
US05703158

反応ノート

読み込み中…