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Water → Alumina

HRID 19423
ノート
印刷プレビュー

反応式

HRID 19423 の反応式
CC(C)[O-:3].[Al+3:5].CC(C)[O-:8].CC(C)[O-:12].CC([OH:17])C.[OH2:18]>CC(O)(CC(O)C)C>[O-2:3].[O-2:8].[O-2:12].[Al+3:5].[Al+3:5].[OH-:17].[Al+3:5].[OH-:18].[OH-:3]
参加物実験手順後処理出典と根拠反応ノート

参加物

6

反応物 3

HCID 962WaterHCID 3776IsopropanolHCID 11143Aluminum isopropoxide3 回

生成物 2

HCID 9989226AluminaHCID 10176082Aluminum Hydroxide

試薬・触媒・溶媒 1

HCID 7870Hexylene Glycol溶媒2 回

実験手順

γ-Alumina support was prepared by utilizing a complexing agent-assisted sol gel method. 500 grams of aluminum isopropoxide (AIP) (98%+, Aldrich Chemical Company, Inc.) was dissolved in 600 ml of 2-methyl-2,4-pentanediol (MPD) (99% Aldrich Chemical Company, Inc) in a beaker. The resulting mixture was stirred vigorously with a mechanical polyethylene stirrer. Once the mixture was mixed homogenously, the beaker was placed in a constant temperature bath at a temperature of about 120° C. and stirred continuously for about an hour. Once all the AIP was dissolved, a clear yellowish green solution was obtained. The AIP reacts with MPD to yield 2-propanol in the form of a vapor at the 120° C. reaction condition and the solution begins to gel. Once the gelation is completed after 4 hours, 400 ml of water was added to terminate the gelation and yield a white precipitate (aluminum hydroxide). The white solid product was redispersed in water and aged at 90° C. overnight under constant stirring.

後処理

  1. additionOnce the mixture was mixed homogenously
  2. customthe beaker was placed in a constant temperature bath at a temperature of about 120° C.
  3. stirringstirred continuously for about an hour
  4. customa clear yellowish green solution was obtained
  5. customat the 120° C. reaction condition
  6. customto terminate the gelation

出典と根拠

ORDレコード
ord-80730b83415942cc8e8b4bc4d79a0787
出典データセット
uspto-grants-2010_06
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07743602B2

反応ノート

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