6-Nitro-2,3-dihydro-1H-inden-1-amine--hydrogen chloride (1/1) → HCID 23298452、化合物

HRID 1953544ノート

反応式

HRID 1953544 の反応式
[ClH:1].[N+:2]([C:5]1[CH:13]=[C:12]2[C:8]([CH2:9][CH2:10][CH:11]2[NH2:14])=[CH:7][CH:6]=1)([O-])=O>CO.[Pd]>[ClH:1].[NH2:2][C:5]1[CH:13]=[C:12]2[C:8]([CH2:9][CH2:10][CH:11]2[NH2:14])=[CH:7][CH:6]=1

参加物

4

反応物 1

HCID 232984006-Nitro-2,3-dihydro-1H-inden-1-amine--hydrogen chloride (1/1)

生成物 1

HCID 23298452HCID 23298452、化合物

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 887Methanol溶媒

実験手順

To a solution of 6-nitro-1-aminoindane hydrochloride (1.00 g, 4.66 mmol) in MeOH (100 ml) was added a catalytic amount of 10% Pd/C. The mixture was hydrogenated at 50 psi for 1 hr, filtered through celite, and concentrated to give 6-amino-1-aminoindane hydrochloride which was homogeneous by TLC and used immediately in the next step.

後処理

  1. filtrationfiltered through celite
  2. concentrationconcentrated

出典と根拠

ORDレコード
ord-7bfd765364814d34bd05a5b03c247ef8
出典データセット
uspto-grants-2000_09
特許番号
US06117898

反応ノート

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