Potassium thiocyanate → HCID 86660439、化合物
反応式
[CH2:1]([C:3]1([S:6]([O:9]CCCC)(=[O:8])=[O:7])[CH2:5][CH2:4]1)[CH3:2].[S-]C#N.[K+:17]>O1CCOCC1.O>[CH2:1]([C:3]1([S:6]([O-:9])(=[O:8])=[O:7])[CH2:5][CH2:4]1)[CH3:2].[K+:17]参加物
5
反応条件
- 温度
- 100 °C
実験手順
To a solution of butyl 1-ethylcyclopropane-1-sulfonate (0.46 g, 2.23 mmol prepared from Preparation #6 Step A and ethyl iodide using KKK) in 1,4-dioxane (2.79 mL) and water (2.79 mL) was added potassium thiocyanate (0.12 mL, 2.23 mmol). The reaction is heated to about 100° C. for about 16 h. The reaction mixture was cooled to ambient temperature and was concd under reduced pressure to afford potassium 1-ethylcyclopropane-1-sulfonate (0.42 g, 100%) as a white crystalline solid: 1H NMR (400 MHz, DMSO) d 1.70-1.58 (m, 2H), 0.89 (t, J=7.5, 3H), 0.80 (q, J=3.8, 2H), 0.32 (q, J=3.8, 2H).
後処理
- temperatureThe reaction mixture was cooled to ambient temperature
出典と根拠
- ORDレコード
- ord-23aa52721b32488084f88eb1ef647b56
- 出典データセット
- uspto-grants-2013_04
- 特許番号
- US08426411B2
反応ノート
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