Methyl Benzoate → HCID 67530967、化合物

反応式

[C:1]([O:9][CH3:10])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[NH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20]CO.C(OC(C)C)(C)C>>[C:1]([O:9][CH2:10][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][NH2:11])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

反応物 3

HCID 7150Methyl Benzoate

HCID 7914Diisopropyl Ether

HCID 446535510-Amino-1-decanol

生成物 1

HCID 67530967HCID 67530967、化合物収率 90%

実験手順

In an argon atmosphere, a mixture of methyl benzoate (3.0 mmol), 10-aminodecan-1-ol (3.6 mmol), Zn4(OCOCF3)6O (1.25 mol % in terms of mole number) and diisopropyl ether (5.0 ml) was heated to reflux for 20 hours, and as a result, 10-aminodecyl benzoate was obtained at a yield of 90%. The yield of 10-benzoylaminodecyl benzoate was 7%.