Diethyl Ether → HCID 178470183、化合物
反応式
[ClH:1].C(S[C:10]([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[NH:11])C1C=CC=CC=1.[NH2:18][CH:19]([C:25]#[N:26])[C:20]([O:22][CH2:23][CH3:24])=[O:21].C(OCC)C>C(Cl)(Cl)Cl>[ClH:1].[NH2:26][C:25]1[NH:11][C:10]([C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)=[N:18][C:19]=1[C:20]([O:22][CH2:23][CH3:24])=[O:21]参加物
5
実験手順
Phenylformimino benzyl thioether hydrochloride (28.5gm) was refluxed in chloroform (200 ml) with ethyl aminocyanoacetate (17.0gm) for 1 hour. On standing for 8 hours the addition of dry diethyl ether (250 ml) caused the precipitation of the 5-amino-4-carbethoxy-2-phenylimidazole hydrochloride (24.5gm) m.p. 228° C after recrystallisation from ethanol.
後処理
- customthe precipitation of the 5-amino-4-carbethoxy-2-phenylimidazole hydrochloride (24.5gm) m.p. 228° C
- customafter recrystallisation from ethanol
出典と根拠
- ORDレコード
- ord-863fab730cb44556a1679fb31514b0a7
- 出典データセット
- uspto-grants-1976_12
- 特許番号
- US03997518
反応ノート
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