Sodium Hydroxide → HCID 13105374、化合物

HRID 1981224ノート

反応式

HRID 1981224 の反応式
[Br-].[CH2:2]([P+:13](C1C=CC=CC=1)([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[OH-:32].[Na+]>CO>[C:14]1([P:13](=[O:32])([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 3085198Triphenylundecylphosphonium bromide

生成物 1

HCID 13105374HCID 13105374、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

反応条件

温度
50 °C

実験手順

A stirred mixture of undecyl-triphenyl-phosphonium bromide (45.7 g), methanol (300 ml) and 2M sodium hydroxide solution (300 ml) was heated at 50° C. for 3 hours and then concentrated under vacuum until the oily product solidified. The solid was washed with water, dried and recrystallised from petroleum spirit to give diphenyl-undecylphosphine oxide, m.p. 69° C.

後処理

  1. concentrationconcentrated under vacuum until the oily product
  2. washThe solid was washed with water
  3. customdried
  4. customrecrystallised from petroleum spirit

出典と根拠

ORDレコード
ord-1c0e950b3fd34abab60053214776d4d6
出典データセット
uspto-grants-1985_04
特許番号
US04513005

反応ノート

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