化工社化工社 化学情報印刷レポート · 研究参考用
Ethyl tert-butyl ether → Hydrogen Peroxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl tert-butyl ether | HCID 12512 | — |
| 反応物 | Ozone | HCID 24823 | — |
| 反応物 | Ozone Hydrogen Peroxide | HCID 86602708 | — |
| 溶媒 | tert-Butyl methyl ether | HCID 15413 | — |
| 生成物 | Hydrogen Peroxide | HCID 784 | — |
| 生成物 | tert-Butyl Formate | HCID 61207 | — |
反応手順
Referring to FIG. 12, primary and secondary reactions of MTBE with Ozone are shown. Karpel vel Leitner, R. N., A. L Papailhous, J. P. Crove, J. Payrot, and M. Dore (1994) “Oxidation of Methyl tert-Butyl Ether (MTBE) and Ethyl tert-Butyl Ether (ETBE) by Ozone and Combined Ozone/Hydrogen Peroxide” Ozone Science and Engineering 16, 41-54, described reaction pathways of ozone and MTBE in dilute aqueous solution using controlled experimental conditions. The primary reaction (90% of the consumed mass of MTBE) results in the formation of tert-butyl formate and hydrogen peroxide. A second parallel reaction (less than 10% of the consumed mass of MTBE) generates formaldehyde, TBA, and oxygen.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07547388B2 |
| 出典データセット | uspto-grants-2009_06 |
| ORD ID | ord-30a8bffd86224d9a87fcbdb6db2904f4 |
| 出典メモ | uspto-grants-2009_06 |