Hydrazine hydrate (1:1) → (1SR,8RS)-5-(2,2-Dimethyl-propyl)-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6,-triene

反応式

[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[C:3](=O)[C:2]2=O.COP([CH2:16][C:17](=O)[CH2:18][C:19]([CH3:22])([CH3:21])[CH3:20])(=O)OC.O.[NH2:25][NH2:26]>>[CH3:20][C:19]([CH3:22])([CH3:21])[CH2:18][C:17]1[CH:16]=[C:3]2[C:2]([CH:1]3[CH2:7][CH:4]2[CH2:5][CH2:6]3)=[N:26][N:25]=1

参加物

反応物 3

HCID 24654Hydrazine hydrate (1:1)

HCID 138696Bicyclo(2.2.1)heptane-2,3-dione

HCID 25112585(4,4-Dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester

生成物 1

HCID 69059352(1SR,8RS)-5-(2,2-Dimethyl-propyl)-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6,-triene

実験手順

light-yellow solid. MS (ESI): 217.2 (MH+). Prepared from bicyclo[2.2.1]heptan-2,3-dione, (4,4-dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.

出典と根拠

ORDレコード: ord-c576137db1a9438987e20392dca4a2c0
出典データセット: uspto-grants-2009_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07547697B2

反応ノート

読み込み中…