Sodium methanethiolate → HCID 18434372、化合物
反応式
[Br:1][C:2]1[CH:7]=[CH:6][C:5](CBr)=[C:4]([N+:10]([O-:12])=[O:11])[CH:3]=1.[CH3:13][S-:14].[Na+]>O1CCCC1>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:14][CH3:13])=[C:4]([N+:10]([O-:12])=[O:11])[CH:3]=1参加物
4
実験手順
A suspension of 4-bromo-1-(bromomethyl)-2-nitrobenzene (1.0 g) and sodium methanethiolate (0.285 g) in tetrahydrofuran (20 ml) was stirred under nitrogen for 60 h. The solvent was evaporated, chloroform (50 ml) was added and the rsidual solid was removed by filtration. The filtrate was comncentrated under vacuum to give the title compound (0.89 g).
後処理
- customThe solvent was evaporated
- additionchloroform (50 ml) was added
- customthe rsidual solid was removed by filtration
出典と根拠
- ORDレコード
- ord-9f04f6de723e4ac1822b9b8dab7cc130
- 出典データセット
- uspto-grants-2010_01
- 特許番号
- US07642276B2
反応ノート
読み込み中…