Dicumyl peroxide → Bis(1,2,2,6,6-pentamethyl-4-piperidyl)tetrahydrophthalate bis(1,2,2,6,6-pentamethyl-4-piperidyl)fumarate

HRID 1995422

反応式

HRID 1995422 の反応式
[CH3:1][N:2]1[C:7]([CH3:9])([CH3:8])[CH2:6][CH:5]([O:10][C:11](=[O:32])[CH:12]2[CH:31]=[CH:30][CH2:29][CH2:28][CH:13]2[C:14]([O:16][CH:17]2[CH2:22][C:21]([CH3:24])([CH3:23])[N:20]([CH3:25])[C:19]([CH3:27])([CH3:26])[CH2:18]2)=[O:15])[CH2:4][C:3]1([CH3:34])[CH3:33].[CH3:35][N:36]1[C:41]([CH3:43])([CH3:42])[CH2:40][CH:39](/[C:44](/[C:60]([O-:62])=[O:61])=[C:45](/[CH:49]2[CH2:54][C:53]([CH3:56])([CH3:55])[N:52]([CH3:57])[C:51]([CH3:59])([CH3:58])[CH2:50]2)\[C:46]([O-:48])=[O:47])[CH2:38][C:37]1([CH3:64])[CH3:63].C(OOC(C1C=CC=CC=1)(C)C)(C1C=CC=CC=1)(C)C>>[CH3:25][N:20]1[C:21]([CH3:23])([CH3:24])[CH2:22][CH:17]([O:16][C:14](=[O:15])[CH:13]2[CH:28]=[CH:29][CH2:30][CH2:31][CH:12]2[C:11]([O:10][CH:5]2[CH2:6][C:7]([CH3:8])([CH3:9])[N:2]([CH3:1])[C:3]([CH3:33])([CH3:34])[CH2:4]2)=[O:32])[CH2:18][C:19]1([CH3:27])[CH3:26].[CH3:57][N:52]1[C:53]([CH3:55])([CH3:56])[CH2:54][CH:49](/[C:45](/[C:46]([O-:48])=[O:47])=[C:44](/[CH:39]2[CH2:40][C:41]([CH3:42])([CH3:43])[N:36]([CH3:35])[C:37]([CH3:64])([CH3:63])[CH2:38]2)\[C:60]([O-:62])=[O:61])[CH2:50][C:51]1([CH3:59])[CH3:58]

参加物

4

反応物 3

HCID 6641Dicumyl peroxideHCID 53844409Bis(1,2,2,6,6-pentamethyl-4-piperidyl)tetrahydrophthalateHCID 86739024Bis(1,2,2,6,6-pentamethyl-4-piperidyl)fumarate

生成物 1

HCID 86739023Bis(1,2,2,6,6-pentamethyl-4-piperidyl)tetrahydrophthalate bis(1,2,2,6,6-pentamethyl-4-piperidyl)fumarate

反応条件

温度
150 °C

実験手順

Bis(1,2,2,6,6-pentamethyl-4-piperidyl)tetrahydrophthalate 1.3 g (1/370 mole), bis(1,2,2,6,6-pentamethyl-4-piperidyl)fumarate 2.1 g (1/200 mole) and dicumyl peroxide 0.034 g were heated and stirred at 150° C. for eight hours, and then cooled to obtain a pale yellow solid.

後処理

  1. temperaturecooled
  2. customto obtain a pale yellow solid

出典と根拠

ORDレコード
ord-6f5f5d977fd54575a8e2ab7c7258a3ee
出典データセット
uspto-grants-1983_09
特許番号
US04404301

関連ノート

読み込み中…