Benzyl Alcohol → Phenol
反応式
[Ni:1].C[OH:3].[CH2:4]([OH:11])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1>C1C=CC=CC=1>[C:5]1([OH:3])[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[Ni:1].[CH3:4][OH:11]参加物
5
実験手順
[2,2'-thiobis-(4-t-octyl-phenolato)]-benzyl alcohol Nickel II, NiTBP.C6H5OH was prepared as follows: p [2,2'-thiobis-(4-t-octylphenolato)]-2-propanol nickel II prepared as described in Example 4 (83.9 g) was dissolved in benzene (250 ml) and benzyl alcohol (16.2 g) was then added. The resulting solution was heated and refluxed for 1 hr. The displaced 2-propanol and most of the benzene solvent was then removed by distillation and the remainder by rotary evaporation. The complex[2,2'-thiobis-(4-t-octylphenolato)]benzyl alcohol nickel II was thus obtained as a green solid which softened at 150° C., melted partially at 210° C. and was completely fused at 260° C.
後処理
- temperatureThe resulting solution was heated
- temperaturerefluxed for 1 hr
- customThe displaced 2-propanol and most of the benzene solvent was then removed by distillation
- customthe remainder by rotary evaporation
出典と根拠
- ORDレコード
- ord-b58532c9e4624da39029dc8838fa7f8d
- 出典データセット
- uspto-grants-1980_04
- 特許番号
- US04198303
反応ノート
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