1-Iodopropane → HCID 20330058、化合物

反応式

[C:1]([C:4]1[C:5]([N:16]=[CH:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[C:6]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[NH:7][C:8]=1[CH3:9])(=[O:3])[CH3:2].[CH2:24](I)[CH2:25][CH3:26]>>[C:1]([C:4]1[C:5]([N:16]=[CH:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[C:6]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[N:7]([CH2:24][CH2:25][CH3:26])[C:8]=1[CH3:9])(=[O:3])[CH3:2]

参加物

反応物 2

HCID 336431-Iodopropane

HCID 12789002HCID 12789002、化合物

生成物 1

HCID 20330058HCID 20330058、化合物

実験手順

Starting from the compound of Example 46 and propyl iodide, and using procedure (a) of Example 49, 4-acetyl-3-benzylideneamino-5-methyl-2-phenyl-1-propylpyrrole is obtained as an oily substance.This compound is hydrolyzed as in procedure (b) of Example 49. Yield of the title compound: 50%, m.p. 113°-15° C. (from ethanol).

出典と根拠

ORDレコード: ord-d55a9da145ad4a719521d0342763487b
出典データセット: uspto-grants-1980_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04198502

反応ノート

読み込み中…