(Bromodichloromethyl)phenylmercury → HCID 20344549、化合物

HRID 2049839

反応式

HRID 2049839 の反応式
[Cl:1][C:2]1[CH:14]=[CH:13][C:5]([O:6][CH:7]=[CH:8][C:9]([O:11][CH3:12])=[O:10])=[CH:4][CH:3]=1.C1([Hg][C:22](Br)([Cl:24])[Cl:23])C=CC=CC=1>C1C=CC=CC=1>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([O:6][CH:7]2[CH:8]([C:9]([O:11][CH3:12])=[O:10])[C:22]2([Cl:24])[Cl:23])=[CH:13][CH:14]=1

参加物

4

反応物 2

HCID 76800(Bromodichloromethyl)phenylmercuryHCID 53663470Methyl 3-(4-chlorophenoxy)prop-2-enoate

生成物 1

HCID 20344549HCID 20344549、化合物

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

A mixture of methyl 3-(4-chlorophenoxy)-2-propenoate (30 mmol), phenyl(bromodichloromethyl)mercury (30 mmol) and 50 ml benzene are heated under reflux, with stirring, for 4 hr, followed by TLC of the product. The mixture is then filtered and the solvent removed, giving methyl 3-(4-chlorophenoxy)-2,2-dichlorocyclopropanecarboxylate, which is then hydrolyzed and reacted with m-phenoxybenzyl bromide to give m-phenoxybenzyl 3-(4-chlorophenoxy)-2,2-dichlorocyclopropanecarboxylate.

後処理

  1. temperatureare heated
  2. temperatureunder reflux
  3. filtrationThe mixture is then filtered
  4. customthe solvent removed

出典と根拠

ORDレコード
ord-08344fd5ddcf45489bc6732e73bd2fc0
出典データセット
uspto-grants-1980_04
特許番号
US04198527

関連ノート

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