Nitric Acid → HCID 20342728、化合物

HRID 2049898ノート

反応式

HRID 2049898 の反応式
CCOCC.[C:6]1([CH3:16])[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[O:12][CH:13]([CH3:15])[CH3:14].C(OC(=O)C)(=O)C.[N+:24]([O-])([OH:26])=[O:25]>C(O)(=O)C.O>[CH:13]([O:12][C:7]1[CH:8]=[CH:9][C:10]([N+:24]([O-:26])=[O:25])=[CH:11][C:6]=1[CH3:16])([CH3:14])[CH3:15]

参加物

7

反応物 4

HCID 944Nitric AcidHCID 3283Diethyl EtherHCID 7918Acetic AnhydrideHCID 141785Benzene, 1-methyl-2-(1-methylethoxy)-

生成物 1

HCID 20342728HCID 20342728、化合物

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒2 回HCID 962Water溶媒

反応条件

温度
6 °C

実験手順

To a chilled (6° C.) solution contaning 31.8 g (0.2 mol) of the ether prepared as in (a) above and 28.7 g of acetic anhydride in 200 ml of glacial acetic acid was added dropwise a solution of 13.9 g (0.22 mol) of 90% nitric acid in 100 ml of glacial acetic acid. The reaction mixture was allowed to stand at ambient temperature for 12 hours, poured into water and extracted with methylene chloride. The extract was washed with 5% sodium carbonate, water, dried, and concentrated to give 21.8 g of product as an amber oil.

後処理

  1. extractionextracted with methylene chloride
  2. washThe extract was washed with 5% sodium carbonate, water
  3. customdried
  4. concentrationconcentrated

出典と根拠

ORDレコード
ord-841dcbfdc1dd48bb82b15ea78b8659d0
出典データセット
uspto-grants-1980_04
特許番号
US04199347

反応ノート

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