Ammonia → 3-Phenoxybenzamide

HRID 2052137ノート

反応式

HRID 2052137 の反応式
[NH3:1].[O:2]([C:9]1[CH:10]=[C:11]([CH:15]=[CH:16][CH:17]=1)[C:12](Cl)=[O:13])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>C(Cl)(Cl)Cl>[O:2]([C:9]1[CH:10]=[C:11]([CH:15]=[CH:16][CH:17]=1)[C:12]([NH2:1])=[O:13])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

4

反応物 2

HCID 222AmmoniaHCID 27603413-Phenoxybenzoyl chloride

生成物 1

HCID 166186253-Phenoxybenzamide

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

Saturated with anhydrous ammonia a solution containing 23 g (0.1 mole) of 3-phenoxybenzoyl chloride and 250 ml of AR chloroform. Continued stirring for 30 min., chilled to 0° and filtered. The product was pulverised, triturated in cold water and oven-dried to give 21.3 g, m.p. 127°-128°.

後処理

  1. temperaturechilled to 0°
  2. filtrationfiltered
  3. customtriturated in cold water
  4. customoven-dried
  5. customto give 21.3 g, m.p. 127°-128°

出典と根拠

ORDレコード
ord-a39fde958b4e4272b8722604470a7011
出典データセット
uspto-grants-1980_01
特許番号
US04182881

反応ノート

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