Acetic Anhydride → alpha-(2-Acetoxy-5-sulfophenylazo)acetoacetanilide

HRID 2052199ノート

反応式

HRID 2052199 の反応式
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([OH:11])(=[O:10])=[O:9])=[CH:4][C:3]=1[N:12]=[N:13][CH:14]([C:24]([CH3:26])=[O:25])[C:15]([NH:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)=[O:16].[C:27](OC(=O)C)(=[O:29])[CH3:28]>N1C=CC=CC=1>[C:27]([O:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([OH:11])(=[O:10])=[O:9])=[CH:4][C:3]=1[N:12]=[N:13][CH:14]([C:24]([CH3:26])=[O:25])[C:15]([NH:17][C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)=[O:16])(=[O:29])[CH3:28]

参加物

4

反応物 2

HCID 7918Acetic AnhydrideHCID 135839437alpha-(2-Hydroxy-5-sulfophenylazo)acetoacetanilide

生成物 1

HCID 23336111alpha-(2-Acetoxy-5-sulfophenylazo)acetoacetanilide

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

α-(2-hydroxy-5-sulfophenylazo)acetoacetanilide (40 g) was dissolved in boiling pyridine (750 ml) and acetic anhydride (100 ml) added. Some material precipitated while the reaction mixture was hot. After being cooled, the product was filtered off and dried. Yield: 38 g.

後処理

  1. additionadded
  2. customSome material precipitated while the reaction mixture
  3. temperatureAfter being cooled
  4. filtrationthe product was filtered off
  5. customdried

出典と根拠

ORDレコード
ord-dc614a1fcf76419a9bcd9dce6a459e38
出典データセット
uspto-grants-1980_01
特許番号
US04183755

反応ノート

読み込み中…