Triethylamine → (+/-)-5-(2,6-Dichlorophenyl)-3-(3-nitrophenyl)-2-isoxazoline
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([C:10](Cl)=[N:11][OH:12])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Cl:14][C:15]1[CH:22]=[CH:21][CH:20]=[C:19]([Cl:23])[C:16]=1[CH:17]=[CH2:18].C(N(CC)CC)C>C1COCC1>[Cl:14][C:15]1[CH:22]=[CH:21][CH:20]=[C:19]([Cl:23])[C:16]=1[CH:17]1[O:12][N:11]=[C:10]([C:6]2[CH:7]=[CH:8][CH:9]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=2)[CH2:18]1参加物
5
実験手順
3-Nitro-N-hydroxybenzenecarboximidoyl chloride (1.16 g, 5.78 mmol) and 2,6-dichlorostyrene (1.0 g, 5.78 mmol) were dissolved in anhydrous THF (20 mL) and triethylamine (1.21 mL, 8.67 mmol). Upon addition of triethylamine a while solid formed. After 3 h this solid was collected by filtration under reduced pressure to provide the title compound as a white solid.