Potassium Permanganate → 1-Ethyl-5-butyryl-6-methyl-benzimidazole-2-carboxylic acid

HRID 2058018ノート

反応式

HRID 2058018 の反応式
[CH2:1]([N:3]1[C:7]2[CH:8]=[C:9]([CH3:17])[C:10]([C:12](=[O:16])[CH2:13][CH2:14][CH3:15])=[CH:11][C:6]=2[N:5]=[C:4]1[CH2:18][OH:19])[CH3:2].[Mn]([O-])(=O)(=O)=[O:21].[K+]>>[CH2:1]([N:3]1[C:7]2[CH:8]=[C:9]([CH3:17])[C:10]([C:12](=[O:16])[CH2:13][CH2:14][CH3:15])=[CH:11][C:6]=2[N:5]=[C:4]1[C:18]([OH:21])=[O:19])[CH3:2]

参加物

3

反応物 2

HCID 516875Potassium PermanganateHCID 130606811-Ethyl-5-butyryl-6-methyl-benzimidazole-2-methanol

生成物 1

HCID 128066581-Ethyl-5-butyryl-6-methyl-benzimidazole-2-carboxylic acid

実験手順

In a manner analogous to that described in Example 12, 5.2 g of 1-ethyl-5-butyryl-6-methyl-benzimidazole-2-methanol can be oxidised with 4.5 g of potassium permanganate to give 1-ethyl-5-butyryl-6-methyl-benzimidazole-2-carboxylic acid with a melting point>80° (decomposition).

出典と根拠

ORDレコード
ord-616922b2c8684cef9c3594069e652739
出典データセット
uspto-grants-1980_07
特許番号
US04213993

反応ノート

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