4-{[(2,2-Dichlorocyclopropyl)methyl]sulfanyl}-2-nitroaniline → HCID 20532837、化合物

HRID 2071430ノート

反応式

HRID 2071430 の反応式
[Cl:1][C:2]1([Cl:17])[CH2:4][CH:3]1[CH2:5][S:6][C:7]1[CH:13]=[CH:12][C:10]([NH2:11])=[C:9]([N+:14]([O-])=O)[CH:8]=1>C(O)C.O=[Pt]=O>[Cl:17][C:2]1([Cl:1])[CH2:4][CH:3]1[CH2:5][S:6][C:7]1[CH:13]=[CH:12][C:10]([NH2:11])=[C:9]([NH2:14])[CH:8]=1

参加物

4

反応物 1

HCID 205328394-{[(2,2-Dichlorocyclopropyl)methyl]sulfanyl}-2-nitroaniline

生成物 1

HCID 20532837HCID 20532837、化合物

試薬・触媒・溶媒 2

HCID 345198Adams' catalyst触媒HCID 702Ethanol溶媒

実験手順

A mixture of 8.8 g (0.03 mole) of 4-[(2,2-dichlorocyclopropyl)methyl]thio-2-nitroaniline and 0.6 g of PtO2 in 200 ml of absolute ethanol is reduced on the Parr hydrogenator at 50 psi until the theoretical amount of H2 is absorbed. The mixture is filtered and the solvent is removed in vacuo to yield a dark oil.

後処理

  1. customis absorbed
  2. filtrationThe mixture is filtered
  3. customthe solvent is removed in vacuo
  4. customto yield a dark oil

出典と根拠

ORDレコード
ord-7439281ecbd54d4fa2c5e3e5f497e190
出典データセット
uspto-grants-1977_09
特許番号
US04046908

反応ノート

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