1,2-Dichlorobenzene → Hexachloroindene
反応式
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[Cl:8].[Cl:9][C:10](Cl)(Cl)[C:11]([Cl:15])=[C:12](Cl)[Cl:13].[Cl:18]C(Cl)=C(Cl)Cl>>[Cl:1][C:2]1[CH:7]=[C:6]2[C:5]([C:10]([Cl:9])=[C:11]([Cl:15])[CH:12]2[Cl:13])=[C:4]([Cl:18])[C:3]=1[Cl:8]参加物
4
反応条件
- 温度
- 125 °C
実験手順
A mixture containing 29.4 grams (0.2 mole), of ortho-dichlorobenzene, 50 grams (0.2 moles) of hexachloropropylene and 2.5 grams of ferric chloride in 250 milliliters of perchloroethylene was heated and stirred by the process of Example I for about 4 hours at reflux (125° C.). The reaction mixture was then washed with concentrated hydrochloric acid, then water and distilled to give a 48.7% yield of hexachloroindene. The product was confirmed by infrared and NMR spectra analysis as structured.
後処理
- additionA mixture containing 29.4 grams (0.2 mole)
- washThe reaction mixture was then washed with concentrated hydrochloric acid
- distillationwater and distilled
出典と根拠
- ORDレコード
- ord-ebe79f31ccfc476ca69a935b53df9376
- 出典データセット
- uspto-grants-1977_09
- 特許番号
- US04049727
反応ノート
読み込み中…