tert-Butoxy bis(dimethylamino)methane → HCID 67096156、化合物

反応式

[CH2:1]([O:3][CH:4]1[CH2:9][CH2:8][CH2:7][CH2:6][C:5]1=[O:10])[CH3:2].C(O[CH:16](N(C)C)[N:17]([CH3:19])[CH3:18])(C)(C)C>>[CH3:16][N:17]([CH3:19])[CH:18]=[C:6]1[CH2:7][CH2:8][CH2:9][CH:4]([O:3][CH2:1][CH3:2])[C:5]1=[O:10]

参加物

反応物 2

HCID 79885tert-Butoxy bis(dimethylamino)methane

HCID 27333302-Ethoxycyclohexanone

生成物 1

HCID 67096156HCID 67096156、化合物

実験手順

2-Ethoxy-cyclohexanone (142 mg, 1.0 mmol) was reacted with tert.-butoxy-bis-(dimethylamino)-methane using in analogous manner the procedure described in example 45a) to give crude title compound (232 mg) as a yellow oil which was used directly in the next step.

出典と根拠

ORDレコード: ord-9bd04d5851be433f98fbd026f976847d
出典データセット: uspto-grants-2011_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07923450B2

反応ノート

読み込み中…